Two important steps of slow thermal decomposition of azides have been studied using the method of statistical mechanics. Relations of the transform-ratio(α) of reactional equilibrium to temperature and pressure are formalized and the reaction mechanism is briefly discussed.

  • 用统计力学方法对无机叠氮化物慢速热分解中的两步重要反应进行了研究,求得了反应平衡转化率α随温度T和压力P变化的表达式,并对反应机理作了分析和探讨。

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